For $F$ to be a CDF, it must fulfill 3 properties.
- $F$ must be monotonically increasing.
- $\lim_{x \to - \infty} F(X) = 0$
- $\lim_{x \to \infty} F(X) = 1$
Since $F(x) = 1$ for any $x \geq 1$, $\lim_{x \to \infty} F(X) = 1$. Since $F(x) = 0$ for any $x \leq 0$, $\lim_{x \to - \infty} F(X) = 0$.
To see if $F$ is monotonically increasing, we suggest that you try graphing it to get some intuition. Since $F$ is continuous, we can take its derivative and check if it's always nonnegative.
$$ \frac{d}{dx} F(x) = \frac{d}{dx} 3x-2x^2 = 3 - 4x$$
We can notice quickly that there is an inflection point at $x=\frac{3}{4}$, and a quick spot-evaluation (without even using any further calculus identities) shows that for $\frac{3}{4} \leq x \leq 1$ this function is decreasing. And so, it does not meet the definition of a valid cdf.